Publication List of Prof. Antonio Togni

2012

Nagano, T.; Iimuro, A.; Schwenk, R.; Ohshima, T.; Kita, Y.; Togni, A.; Mashima, K. "Additive Effects of Amines on Asymmetric Hydrogenation of Quinoxalines Catalyzed by Chiral Iridium Complexes" Chem. Eur. J. 2012, 18, 11578-11592.

De Magalhães, H. P.; Lüthi, H. P.; Togni, A. "Reductive Eliminations from λ³-Iodanes: Understanding Selectivity and the Crucial Role of the Hypervalent Bon" Chem. Rev. 2012, 108, 5299-5358.

Niedermann, K.; Früh, N.; Senn, R.; Czarniecki, B.; Verel, R.; Togni, A. "Direct Electrophilic N-Trifluoromethylation of Azoles by a Hypervalent Iodine Reagent" Angew. Chem. Int. Ed. 2012, 51, 6511-6515.

Barreiro, E. M.; Broggini, D. F. D.; Adrio, L. A.; White, A. J. P.; Schwenk, R.; Togni, A.; Hii, K. K. "Gold(I) Complexes of Conformationally Constricted Chiral Ferrocenyl Phosphines" Organometallics 2012, 31, 3745-3754.

Bertogg, A.; Hintermann, L.; Huber, D. P.; Perseghini, M.; Sanna, M.; Togni, A. "Substrate Range of the Titanium TADDOLate Catalyzed Asymmetric Fluorination of Activated Carbonyl Compounds" Helv. Chim. Acta 2012, 95, 353-403.

Mejía, E.; Togni, A. "Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents" ACS Catal. 2012, 2, 521-527.

Santschi, N.; Geissbühler, P.; Togni, A. "Reactivity of an electrophilic hypervalent iodine trifluoromethylation reagent with hydrogen phosphates – A mechanistic study" J. Fluorine Chem. 2012, 135, 83-86.

Buergler, J. F.; Niedermann, K.; Togni, A. "P-Stereogenic Trifluoromethyl Derivatives of Josiphos: Synthesis, Coordination Properties, and Application in Asymmetric Catalysis" Chem. Eur. J. 2012, 18, 632-640.

2011

Matoušek, V.; Togni, A.; Bizet, V.; Cahard, D. "Synthesis of α-CF₃-Substituted Carbonyl Compounds with Relative and Absolute Stereocontrol Using Electrophilic CF₃-Transfer Reagents" Organic Lett. 2011, 13, 5762-5765.

Hintermann, L.; Perseghini, M.; Togni, A. "Development of the titanium-TADDOLate-catalyzed asymmetric fluorination of β-ketoesters" Beilstein J. Org. Chem. 2011, 7, 1421-1435.

Mejía, E.; Togni, A. "Rhenium Complexes Containing the Chiral Tridentate Ferrocenyl Ligand Pigiphos" Organometallics 2011, 30, 4765-4770.

Buergler, J. F.; Togni, A. "Secondary Ferrocenyl Phosphines: Versatile Precursors for the Synthesis of Bi- and Tridentate Ligands" Organometallics 2011, 30, 4742-4750.

Charkoudian, L. K.; Liu, C. W.; Capone, S.; Kapur, S.; Cane, D. E.; Togni, A.; Seebach, D.; Khosla, C."Probing the Interactions of an Acyl Carrier Protein Domain from the 6-Deoxyerythronolide B Synthase" Protein Sci. 2011, 20, 1244-1255.

Flückiger, M.; Togni, A. "Iron(II)-Catalyzed Asymmetric Hydrosilylation of Acetophenone" Eur. J. Org. Chem. 2011, 4353-4360.

Santschi, N.; Togni, A. "Electrophilic Trifluoromethylation of S-Hydrogen Phosphorothioates" J. Org. Chem. 2011, 76, 4189-4193.

Buergler, J. F.; Togni, A."Chiral Trifluoromethylphosphines: A New Stereoselective Synthesis of Josiphos-type Ligands Containing Two Stereogenic Phosphorus Atoms" Chem. Comm. 2011, 47, 1896-1898.

Niedermann, K.; Früh, N.; Vinogradova, E.; Wiehn, M.S.; Moreno, A.; Togni, A. "Eine Ritter-Reaktion: direkte elektrophile Trifluoromethylierung von Stickstoffzentren mit hypervalenten Iodreagentien" Angew. Chem. 2011, 123, 1091-1095 (Angew. Chem. Int. Ed. 2011, 50, 1059- 1063).

Eisenberger, P.; Kieltsch, I.; Koller, R.; Stanek, K.; Togni, A. "Preparation of a Trifluoromethyl Transfer Agent: 1-Trifluoromethyl-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole" Org. Synth. 2011, 88, 168-180.

Sondenecker, A.; Cvengroì, J.; Aardoom, R.; Togni, A. "P-Stereogenic Ferrocene-Based (Trifluoromethyl)phosphanes: Synthesis, Structure, Coordination Properties and Catalysis" Eur. J. Org. Chem. 2011, 78-87.

2010

Togni, A. "Organofluorine Chemistry: Taking the Next Steps" Adv. Synth. Catal. 2010, 352, 2689-2690.

Wiehn, M. S.; Vinogradova, E. V.; Togni, A. "Electrophilic Trifluoromethylation of Arenes and N-heteroarenes Using Hypervalent Iodine Reagents" J. Fluorine Chem. 2010, 131, 951-957.

Niedermann, K.; Welch, J. M.; Koller, R.; Cvengros, J.; Santschi, N.; Battaglia, P.; Togni, A. "New Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation and their Precursors: Synthesis, Structure, and Reactivity" Tetrahedron 2010, 66, 5753-5761.

Stanek, K.; Czarniecki, B.; Aardoom, R.; Rüegger, H.†; Togni, A. "Remote C-F-Metal Interactions in Late-Transition-Metal Complexes" Organometallics 2010, 29, 2540-2546.

Koller, R.; Togni, A. "Electrophilic Trifluoromethylation of Alcohols" Chimica Oggi/Chemistry Today 2010, 28, 33-35.

Armanino, N.; Koller, R.; Togni, A. "Electrophilic Trifluoromethylation of Primary Phosphines: Synthesis of a P-Bis(trifluoromethyl) Derivative of BINAP"
Organometallics 2010, 29, 1771-1777.

Fantasia, S.; Welch, J. M.; Togni, A. "Reactivity of a Hypervalent Iodine Trifluoromethylating Reagent toward THF: Ring Opening and Formation of Trifluoromethyl Ethers" J. Org. Chem. 2010, 75, 1779-1782.

2009

Stanek, K.; Koller, R.; Kieltsch, I.; Eisenberger, P.; Togni, A.
"1-(Trifluoromethyl)-1,2-benziodoxol-3(1H)-one" e-EROS 2009, Article-Rn01121.

Stanek, K.; Koller, R.; Kieltsch, I.; Eisenberger, P.; Togni, A. "Trifluoromethyl-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole" e-EROS 2009, Article-Rn01120.

Seebach, R.; Widmer, H.; Capone, S.; Ernst, R.; Bremi, T.; Kieltsch, I.; Togni, A.; Monna, D.; Langenegger, D.; Hoyer, D. "NMR-Solution Structures and Affinities for the Human Somatostatin G-Protein-Coupled Receptors hsst1-5 of CF3 Derivatives of Sandostatin® (Octreotide)" Helv. Chim. Acta 2009, 92, 2577-2586.

Koller, R.; Huchet, Q.; Battaglia, P.; Welch, J. M.; Togni, A. "Acid-mediated Formation of Trifluoromethyl Sulfonates from Sulfonic Acids and a Hypervalent Iodine Trifluoromethylating Agent" Chem. Commun. 2009, 5993-5995.

Cvengros, J.; Stolz, D.; Togni, A. "A Concise Synthesis of ortho-Iodobenzyl Alcohols via Addition of ortho-Iodophenyl Grignard Reagent to Aldehydes and Ketones"
Synthesis 2009, 116, 2818-2824.

Althaus, M.; Togni, A.; Mezzetti, A. "Asymmetric Oxidative α-Fluorination of 2-Alkylphenylacetaldehydes with AgHF2 and Ruthenium/PPN Catalysts" J. Fluorine Chem. 2009, 130, 702-707.

Koller, R.; Stanek, K.; Stolz, D.; Aardoom, R.; Niedermann, K.; Togni, A.   
"Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents" Angew. Chem. Int. Ed. 2009, 48, 4332-4336.

2008

Fadini, L.; Togni, A. "Asymmetric Hydroamination of Acrylonitrile Derivatives Catalyzed by NiII-Complexes" Tetrahedron: Asymmetry 2008, 19, 2555-2562.

Capone, S.; Kieltsch, I.; Flögel, O.; Lelais, G.; Togni, A.; Seebach, D.
"Electrophilic S-Trifluoromethylation of Cysteine Chains in α- and β-Peptides. Isolation of Trifluoromethylated Sandostatin (Octreotide) Derivatives" Helv. Chim. Acta 2008, 91, 2035-2055.

Stanek, K.; Koller, R.; Togni, A. "The Reactivitiy of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols" J. Org. Chem. 2008, 73, 7678-7685.

Walz, I.; Togni, A. "Ni(II)-catalyzed Enantioselective Nazarov Cyclizations" Chem. Commun. 2008, 1-3, 4315-4317.

Kieltsch, I.; Eisenberger, P.; Stanek, K.; Togni, A. "Recent Advances in Electrophilic CF3-Transfer Using Hypervalent Iodine(III) Reagents" Chimia 2008, 62, 260-263.

Eisenberger, P.; Kieltsch, I.; Armanino, N.; Togni, A. "Mild Electrophilic Trifluoromethylation of Secondary and Primary Aryl- and Alkylphosphines Using Hypervalent Iodine(III)-CF3 Reagents" Chem. Commun. 2008, 1575-1577.

Blaser, H.-U.; Chen, W.; Camponovo, F.; Togni, A. "Chiral, 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis" in Ferrocenes: Ligands, Materials and Biomulecules, Stepnicka, P. (Ed). John Wiley & Sons, Ltd. 2008.

2007

Althaus, M.; Becker, C.; Togni, A.; Mezzetti, A. "Ruthenium-Catalyzed Asymmetric Electrophilic Fluorination of 1,3-Dicarbonyl Compounds" Organometallics 2007, 26, 5902-5911.

Jereb, M.; Togni, A. "TiIV-Catalyzed Asymmetric Sulfenylation of 1,3-Dicarbonyl Compounds" Chem. Eur. J. 2007, 13, 9384-9392.

Shi, W.-J.; Liu, Y.; Butti, P.; Togni, A. "Gold(I)- and Brønsted Acid-Catalyzed Ring-Opening of Unactivated Vinylcyclopropanes with Sulfonamides" Adv. Synth. Catal. 2007, 349, 1619-1623.

Visentin, F.; Togni, A. "Synthesis and Characterization of Palladium(II) π-Allyl Complexes with Chiral Phosphinocarbene Ligands. Kinetics and Mechanism of Allylic Amination" Organometallics 2007, 26, 3746-3754.

Walz, I.; Bertogg, A.; Togni, A. "Cationic Vanadium(IV) Complexes as Efficient Catalysts for Nazarov Cyclizations" Eur. J. Org. Chem. 2007, 2650-2658.

Ramírez, D.; Huber, D. P.; Togni, A. "Asymmetric Electrophilic Fluorination of α-Nitro Esters" Synlett 2007, 7, 1143-1147.

Fadini, L.; Togni, A. "Asymmetric Catalyic Hydroamination of Activated Olefins in Ionic Liquids" Helv. Chim. Acta 2007, 90, 411-424.

2006

Kieltsch, I.; Eisenberger, P.; Togni, A. "Mild Electrophilic Trifluoromethylation of Carbon- and Sulfur-Centered Nucleophiles by a Hypervalent Iodine(III)-CF3 Reagent" Angew. Chem. 2006, 118, 1-5.

Srisailam, S. K.; Togni, A. "Phthalimide-N-sulfenyl Chloride in the Ti-catalyzed Asymmetric Sulfenylation of β-keto Esters" Tetrahedron: Asymmetry 2006, 17, 2603-2607.

Perseghini, M.; Massaccesi, M.; Liu, Y.; Togni, A. "Structural and Stereochemical Aspects of the Enantioselective Halogenation of 1,3-dicarbonyl Compounds Catalyzed by Ti(TADDOLato) Complexes" Tetrahedron 2006, 62, 7180-7190.

Huber, D. P.; Stanek, K.; Togni, A. "Consecutive Catalytic Electrophilic Fluorination/Amination of β-keto Esters:
Toward α-fluoro-α-amino Acids?" Tetrahedron: Asymmetry 2006, 17, 658-664.

Hintermann, L.; Läng, F.; Maire, P.; Togni, A. "Interactions of Cationic Palladium(II)- and Platinum(II)-η3-Allyl Complexes with Fluoride: Is Asymmetric Allylic Fluorination a Viable Reaction?" Eur. J. Inorg. Chem. 2006, 1397-1412.

Bonaccorsi, C.; Althaus, M.; Becker, C.; Togni, A.; Mezzetti, A. "Chiral Ru/PNNP Complexes in Catalytic and Stoichiometric Electrophilic O- and F-Atom transfer to 1,3-dicarbonyl Compounds" Pure and Appl. Chem. 2006, 78, 391-396.

Magistrato, A.; Togni, A.; Rothlisberger, U. "Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene: Influence of Electronic and Steric Effects on Enantioselectivity and Catalyst Design via Hybrid QM/MM Molecular Dynamics Simulations" Organometallics 2006, 25, 1151-1157.

Eisenberger, P.; Gischig, S.; Togni, A. "Novel 10-I-3 Hypervalent Iodine-Based Compounds for Electrophilic Trifluoromethylation" Chem. Eur. J. 2006, 12, 2579-2586.

Bertogg, A.; Togni. A. "A Novel Chiral Ferrocene-Based Amidine/Amidinato Ligand
and Its Rhodium Complexes" Organometallics 2006, 25, 622 (published online Dec. 22,
2005).

2005

Bertogg, A.; Camponovo, F., Togni, A. "N-Ferrocenyl-Substituted Planar-Chiral N-Heterocyclic Carbenes and Their Pd^II Complexes" Eur. J. Inorg. Chem. 2005, 347 (published online Dec. 2, 2004).

Gischig, S.; Togni, A. "A Dinuclear Copper(I) Complex Containing a Bridging Chiral Tridentate Carbene Ligand" Organometallics 2005, 24, 203 (published online Dec. 21, 2004).

Jereb, M.; Togni, A. "Titanium(IV)-Catalyzed Enantioselective Sulfenylation of b-Ketoesters" Org. Lett. 2005, 7, 4041.

Gischig, S.; Togni, A. "Pd^II Complexes of Tridentate PCP N-Heterocyclic Carbene Ligands: Structural Aspects and Application in Asymmetric Hydroamination of Cyano Olefins" Eur. J. Inorg. Chem. 2005, 4745-4754.

Sadow, A. D.; Togni, A. "Enanatioselective Addition of Secondary Phosphines to
Methacrylonitrile: Catalysis and Mechanism" J. Am. Chem. Soc. 2005, 127, 17012-17024.

2004

R. Dorta, D. Broggini, R. Stoop, H. Rüegger, F. Spindler, A. Togni, “Chiral Xyliphos Complexes for the Catalytic Imine Hydrogenation Leading to the Metolachlor Herbicide: Isolation of Catalyst-Substrate Adducts”, Chem. Eur. J. 2004, 10, 267.

P. Barbaro, C. Bianchini, G. Giambastiani, D. Masi, S. L. Parisel, A. Togni, “Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Trisphosphines Combining Phosphorus, Planar, and Carbon Chirality”, Synthesis 2004, 3, 345.

Ibrahim, H.; Kleinbeck, F.; Togni, A. "Catalytic Asymmetric Chlorination of b-Keto Esters with Hypervalent Iodine Compounds"Helv. Chim. Acta 2004, 87, 605.

Toullec, P. Y.; Bonaccorsi, C.; Mezzetti, A.; Togni, A."Expanding the Scope of Asymmetric Electrophilic Atom-transfer reactions: Titanium- and Ruthenium-catalyzed hydroxylation of b-Ketoesters" PNAS 2004, 101, 5810.

Fadini, L.; Togni, A. "Ni(II)-PPP Complexes: From the Hydroamination of Activated Olefins to the Synthesis of b-Amino Acids" Chimia 2004, 58, 208.

Gischig, S.; Togni, A. "Synthesis and Coordination Chemistry of a New Chiral Tridentate PCP N-Heterocyclic Carbene Ligand Based on a Ferrocene Backbone" Organometallics 2004, 23, 2479.

Ibrahim, H.; Togni, A. "Enantioselective Halogenation Reactions" Chem. Commun. 2004, 1147.

Magistrato, A.; Woo, T. K.; Togni, A.; Röthlisberger, U. "Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene: Detailed Reaction Mechanism from First-Principles and Hybrid QM/MM Molecular Dynamics Simulation" Organometallics 2004, 23, 3218.

Steiner, I.; Aufdenblatten, R.; Togni, A.; Blaser, H.-U.; Pugin, B. "Novel Silica Gel Supported Chiral Biaryl-diphosphine Ligands for Enantioselective Hydrogenation" Tetrahedron Asym. 2004, 15, 2307.

Dorta, R.; Broggini, D.; Kissner, R.; Togni, A. "Iridium-Imine and –Amine Complexes Relevant to the (S)-Metolachlor Process: Structures, Exchange Kinetics, and C-H Activation by Ir^I Causing Racemization" Chem. Eur. J. 2004, 10, 4546.

Toullec, P. Y.; Devillers, I., Frantz, R., Togni, A. "Relative Electrophilic Fluorinating Power as Assayed by Competitive Catalytic Halogenation Reactions" Helv. Chim. Acta 2004, 87, 2706.

Sadow, A.; Haller, I.; Fadini, L., Togni, A. "Nickel(II)-Catalyzed Highly Enantioselective Hydrophosphination of Methacrylonitrile" J. Am. Chem. Soc. 2004, 126, 14704.

Barbaro, P., Bianchini C., Giambastiani, G., Togni, A. "Chiral Ferrocenyl-Imino Phosphines as Ligands for Palladium-Catalysed Enantioselective Allylic Alkylations in Catalysts for Fine Chemical Synthesis" (Vol. 3, Metal Catalysed Carbon- Carbon Bond-Forming Reactions), Roberts, S. M.; Xiao, J.; Whittall, J.; Pickett, T. (Eds.) John Wiley & Sons, Ltd. 2004.

2003

P. Barbaro, C. Bianchini, G. Giambastiani, A. Togni, “Ruthenium(II) Complexes withTriphospane Ligands Combining Planar, Posphorus, and Carbon Chirality: Application to Asymmetric Reduction of Trifluoroacetophenone”, Eur. J. Inorg. Chem. 2003, 4166.

P. Barbaro, C. Bianchini, G. Giambastiani, A.Togni, “Novel Chiral Ferrocenyl-imino Phosphine Ligands and Their Use in Palladium Catalyzed Allylic Alkylations”, Tetrahedron Lett. 2003, 44, 8279.

A. Togni, “Fluorine in the Life Sciences, Chimia 2003, 57, 570.

R. Dorta, A. Togni, “Addition of the ortho-C-H bonds of phenol across an olefin catalysed by a chiral iridium(I) diphosphine complex”, Chem.Commun. 2003, 760.

R. Frantz, L. Hintermann, M. Perseghini, D. Broggini, A. Togni, “Titanium-Catalyzed Stereoselecive Geminal Heterodihalogenaton of b-Ketoesters”, Org. Lett. 2003, 5, 1709.

L. Hintermann, M. Perseghini, P. Barbaro, A. Togni, “Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity studies”, Eur. J. Inorg. Chem. 2003, 601.

L. Fadini, A. Togni, “Ni(II) Complexes Containing Chiral Tridentate phosphines as New Catalysts for the Hydroamination of Activated Olefins”, Chem. Commun. 2003, 30.

2002

P. Barbaro, C. Bianchini, G. Giambastiani, A. Togni, “The First Tridentate Phosphine Ligand Combining Planar, Phosphorus and Carbon Chirality”, Chem. Commun. 2002, 2672.

H.-U. Blaser, B. Pugin, F. Spindler, A. Togni, “Enantioselective imine Hydrogenation with IR Diphosphine Catalysts: Fighting Deactivation”, C. R. Chim. 2002, 5, 1.

D. Broggini, A. Togni, “Synthesis and Structure of an Enantiomerically Pure C₂ Symmetric Ferrocenyl Carbene”, Helv. Chim. Acta 2002, 85, 2518.

L. Hintermann, D. Broggini, A. Togni, “Titanium Lewis Acids for Asymmetric Catalysis: Synthesis and Structural Characterization of Dichloro[diolato(2-)-kO, kO’]bis(solvent)titanium ([TiCl₂(diolato)(solvent)₂]) Complexes”, Helv. Chim. Acta 2002, 85, 1597.

S. Piana, I. Devillers, A. Togni, U. Röthlisberger, “The Mechanism of Catalytic Enantioselective Fluorination: Computational and Experimental Studies”, Angewandte Chemie, 2002, 41, 979-982.

H.-U. Blaser, W. Brieden, B. Pugin, F. Spindler, M. Studer, A. Togni, “Solvias Josiphos ligands: from discovery to technical applications”, Topics in Catalysis, 2002, 19, 3-16.

2001

P. Barthazy, A. Togni, A. Mezzetti, “Catalytic Fluorination by Halide Exchange with 16-Electron Ruthenium(II) Complexes. X-ray Structure of [TI(µ-F)₂Ru(dppe)₂]PF₆”, Organometallics 2001, 20, 3472-3477.

M. Perseghini, A. Togni, “Product Subclass 8: Ferrocenes”, in Science of Synthesis (Houben-Weyl, Band 1, Methods of Molecular Transformations), M. Lautens, Ed., Thieme, Stuttgart, 2001.

M. Studer, H.-U. Blaser, A. Togni, “Research Collaboration Between a Small Technology Company and Universities: Results, Opinions, and Conclusions”, Chimia 2001, 55, 715-717.

A. Togni, A. Mezzetti, P. Barthazy, C. Becker, I. Devillers, R. Frantz, L. Hintermann, M. Perseghini, M. Sanna, “Developing Catalytic Enantioselective Fluorination”, Chimia 2001, 55, 801-805.

C. Gambs, G. Consiglio, A. Togni, “Structural Aspects of Palladium and Platinum Complexes With Chiral Diphosphinoferrocenes Relevant to the Regio- and Stereoselective Copolymerization of CO with Propene”, Helv. Chim. Acta 2001, 84, 3105-3126.

C. Köllner, A. Togni, “Synthesis, Characterization, and Application in Asymmetric Catalysis of Dendrimers Containing Chiral Ferrocenyl Diphosphines”, Can. J. Chem. 2001, 79, 1762-1774.

A. Togni, H. Grützmacher, Eds., “Catalytic Heterofunctionalization: From Hydroamination to Hydrozirconation”, Wiley-VCH, Weinheim, 2001.

2000

R. Dorta, A. Togni, “Synthesis and Characterization of Chiral Bis(aminato)iridate(I) and Aminato-Bridged Iridium(I) Complexes”, Helv. Chim. Acta 2000, 83, 119-127.

D. Vasen, A. Salzer, F. Gerhards, H.-J. Gais, R. Stürmer, N.H. Bieler, A. Togni, “Optically Active Transition-Metal Complexes. 10. Bifunctional Arene-Chromium-Tricarbonyl Complexes Derived from (R)-Phenylethanamine: Easily Accessible Planar-Chiral Diphosphines and Their Application in Enantioselective Hydrogenation, Hydroamination, and Allylic Sulfonation”, Organometallics 2000, 19, 539-546.

H.M. Senn, P.E. Blöchl, A. Togni, “Toward an Alkene Hydroamination Catalyst: Static and Dynamic Ab Initio DFT Studies”, J. Am. Chem. Soc. 2000, 122, 4098-4107.

T.K. Woo, G. Pioda, U. Röthlisberger, A. Togni, “Chiral Palladium(II)-Bis(trichlorosilyl) Complexes. Synthesis, Structure, and Combined QM/MM Computational Studies”, Organometallics 2000, 19, 2144-2152.

C. Gambs, S. Chaloupka, G. Consiglio, A. Togni, “Ligand Electronic Effect in Enantioselective Palladium-Catalyzed Copolymerization of Carbon Monoxide and Propene”, Angew. Chem. Int. Ed. 2000, 39, 2486-2488.

P. Barthazy, R.M. Stoop, M. Wörle, A. Togni, A. Mezzetti, “Toward Metal-Mediated C-F Bond Formation. Synthesis and Reactivity of the 16-Electron Fluoro Complex [RuF(dppp)₂]PF₆ (dppp = 1,3-Bis(diphenylphosphino)propane)”, Organometallics 2000, 19, 2844-2852.

L. Hintermann, A. Togni, “Catalytic Enantioselective Chlorination and Bromination of ß-Keto Esters”, Helv. Chim. Acta 2000, 83, 2425-2435.

H.M. Senn, D.V. Deubel, P.E. Blöchl, A. Togni, G. Frenking, “Phosphane Lone-Pair Energies as a Measure of Ligand Donor Strengths and Relation to Activation Energies”, J. Mol. Struct. (Theochem) 2000, 506, 233-242.

R. Aufdenblatten, S. Diezi, A. Togni, “Iridium(I)-Catalyzed Asymmetric Intermolecular Hydroarylation of Norbornene with Benzamide”, Monatsh. Chem. 2000, 131, 1345-1350.

L. Hintermann, A. Togni, “Catalytic Enantioselective Fluorinatoin of B-Ketoesters”, Angew. Chem. Int. Ed. 2000 39, 4359-4362.

1999

P.E. Blöchl, H.M. Senn, A. Togni, “Molecular Reaction Modeling from Ab-Initio Molecular Dynamics”, in Transition State Modeling for Catalysis, D.G. Truhlar, K. Morokuma, Eds., ACS Symposium Series Vol. 721, American Chemical Society, Washington, DC, 1999, pp. 88-99.

S. Zürcher, V. Gramlich, A. Togni, “Germanium-containing Ferrocenes and Ferrocenophanes. Potential Precursors for Ring-opening Polymerizations and 'Germaferrocenes'”, Inorg. Chim. Acta 1999, 291, 355-364.

S. Zürcher, J. Petrig, V. Gramlich, M. Wörle, C. Mensing, D. von Arx, A. Togni, “Charge-Transfer Salts of Octamethylferrocenyl Thioethers with Organic Acceptors (TCNQ and TCNQF₄) and Trihalides (Br₃^- and I₃^-). Synthesis, Structure, and Physical Properties”, Organometallics 1999, 18, 3679-3689.

S. Zürcher, J. Petrig, M. Perseghini, V. Gramlich, M. Wörle, D. von Arx, A. Togni, “Charge-Transfer Salts of Ferrocene Derivatives with Bis(maleonitriledithiolato)metallate(III) Complexes ([M(mnt)₂]^-, M = Ni, Pt): A Ground-State High-Spin [(Ni(mnt)₂)₂]^2- Dimer”, Helv. Chim. Acta 1999, 82, 1324-1359.

P. Barbaro, C. Bianchini, W. Oberhauser, A. Togni, “Synthesis and Characterization of Chiral Bis-ferrocenyl Triphosphine Ni(II) and Rh(III) Complexes and Their Use as Catalyst Precursors for Acetalization Reactions”, J. Mol. Catal. A 1999, 145, 139-146.

R. Schneider, C. Köllner, I. Weber, A. Togni, “Dendrimers Based on Cyclophosphazene Units and Containing Chiral Ferrocenyl Ligands for Asymmetric Catalysis”, Chem. Commun. 1999, 2415-2416.

U. Burckhardt, D. Drommi, A. Togni, “Synthesis, Structure, and Reactivity of New Chiral Ferrocenyl Pyrazole Ligands”, Inorg. Chim. Acta 1999, 296, 183-194.

P. Barthazy, L. Hintermann, R. M. Stoop, M. Wörle, A. Mezzetti, A. Togni, “Carbon-Fluorine Bond Formation via a Five-Coordinate Fluoro Complex of Ruthenium(II)”, Helv. Chim. Acta 1999, 82, 2448-2453.

A. Togni, N. Bieler, U. Burckhardt, C. Köllner, G. Pioda, R. Schneider, A. Schnyder, “Recent Studies in Asymmetric Catalysis Using Ferrocenyl Ligands”, Pure Appl. Chem. 1999, 71, 1531-1537.

1998

A. Togni, R.L. Halterman, Eds., Metallocenes, Wiley-VCH, Weinheim, 1998.

A. Togni, “New Chiral Ferrocenyl Ligands for Asymmetric Catalysis” in Metallocenes, A. Togni, R.L. Halterman, Eds., Wiley-VCH, Weinheim, 1998.

S. Zürcher, V. Gramlich, D.v. Arx, A. Togni, “Charge-Transfer Salts of Octamethylferrocenyl Thioethers and [M(mnt)₂]^- Complexes (M = Ni, Co, Pt). Synthesis, Structure, and Physical Properties”, Inorg. Chem. 1998, 37, 4015-4021.

C. Köllner, B. Pugin, A. Togni, “Dendrimers Containing Chiral Ferrocenyl Diphosphine Ligands for Asymmetric Catalysis”, J. Am. Chem. Soc. 1998, 120, 10274-10275.

R. Dorta, A. Togni, “Iridium-Assisted, Enantiospecific Aliphatic C-H Activation/Iodination”, Organometallics 1998, 17, 5441-5444.

R. Dorta, A. Togni, “Facile and Reversible O-H and C-H Activation by a Chiral Iridium(I) Complex”, Organometallics 1998, 17, 3423-3428.

R. Dorta, C. Köllner, G. Pioda, A. Togni, “Some new Aspects of Asymmetric Catalysis with Chiral Ferrocenyl Ligands”, Pure Appl. Chem. 1998, 70, 1477-1485.

G. Pioda, A. Togni, “Highly Enantioselective Palladium-catalyzed Hydrosilylation of Norbornene with Trichlorosilane Using Ferrocenyl Ligands”, Tetrahedron: Asymmetry 1998, 9, 3903-3910.

1997

A. Schnyder, A. Togni, U. Wiesli, “Electronic Effects in Asymmetric Catalysis. Synthesis and Structure of Model Rhodium Complexes Containing Ferrocenyl Ligands for the Hydroboration Reaction”, Organometallics 1997, 15, 255-260.

U. Burckhardt, M. Baumann, A. Togni, “A Remarkable Anion Effect on the Enantioselectivity of the Pd-Catalyzed Allylic Amination Using Ferrocenyl Ligands”, J. Am. Chem. Soc. 1997, 119, 155-159.

A. Togni, “New Chiral Ferrocenyl Ligands in Asymmetric Catalysis: Applications and Mechanistic Studies” in Organic Synthesis via Organometallic OSM 5, G. Helmchen, J. Dibo, D. Flubacher, B. Wiese, Eds., Vieweg, Braunschweig, 1997, pp. 185-208.

R. Dorta, P. Egli, F. Zürcher, A. Togni, “The [IrCl(Diphosphine)]₂/Fluoride System. Developing Catalytic Asymmetric Olefin Hydroamination”, J. Am. Chem. Soc. 1997, 119, 10857-10858.

P. Barbaro, C. Bianchini, A. Togni, “Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)-P₃ or P₂S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone”, Organometallics 1997, 16, 3004-3014.

M. Hobi, O. Ruppert, V. Gramlich, A. Togni, “A Stepwise Synthesis of Octamethylferrocene-1,1'-dicarbaldehyde. Preparation of New Electron-Donors for Charge-Transfer Complexes”, Organometallics 1997, 16, 1384-1391.

U. Burckhardt, M. Baumann, G. Trabesinger, V. Gramlich, A. Togni, “A Bimetallic Palladium Catalyst for Asymmetric Allylic Substitution Reaction”, Organometallics 1997, 16, 5252-5259.

1996

A. Togni, “Planar-Chiral Ferrocenes: Synthetic Methods and Applications”, Angew. Chem. 1996, 108, 1581; Angew. Chem. Int. Ed. Engl. 1996, 35, 1475.

A. Togni, “Developing New Chiral Ferrocenyl Ligands for Asymmetric Catalysis: A Personal Account”, Chimia 1996, 50, 86-93.

P. Zanello, G. Opromolla, G. Giorgi, G. Sasso, A. Togni, “Redox Behaviour of Ferrocene Derivatives. 8. 1,1'-Bis(diphenylphosphino)ferrocenes”, J. Organomet. Chem. 1996, 506, 61-65.

A. Togni, U. Burckhardt, V. Gramlich, P.S. Pregosin, R. Salzmann, “Palladium-Catalyzed Asymmetric Allylic Amination Using Ferrocenyl Pyrazole Ligands: Steric Control of h³-Allyl Configuration and Site-Selective Nucleophilic Attack”, J. Am. Chem. Soc. 1996, 118, 1031-1037.

N.C. Zanetti, F. Spindler, J. Spencer, A. Togni, G. Rihs, “Synthesis, Characterization, and Application in Asymmetric Hydrogenation Reactions of Chiral Ruthenium(II) Diphosphine Complexes”, Organometallics 1996, 15, 860-866.

H.C.L. Abbenhuis, U. Burckhardt, V. Gramlich, A. Martelletti, J. Spencer, I. Steiner, A. Togni, “Comparing Chiral Ferrocenyl and Ruthenocenyl Ligands: How Subtle Changes Influence their Performance in Asymmetric Catalysis”, Organometallics 1996, 15, 1614-1621.

U. Burckhardt, V. Gramlich, P. Hofmann, R. Nesper, P.S. Pregosin, R. Salzmann, A. Togni, “Crystallographic and NMR Studies on Chiral Pd(II) Allyl Ferrocene Based P,N Complexes”, Organometallics 1996, 15, 3496-3503.

P.E. Blöchl, A. Togni, “First-Principles Investigation of Enantioselective Catalysis: Asymmetric Allylic Amination with Pd Complexes Bearing Ferrocenyl P,N Ligands”, Organometallics 1996, 15, 4125-4132.

M. Hobi, S. Zürcher, V. Gramlich, U. Burckhardt, C. Mensing, M. Spahr, A. Togni, “Paramagnetic and Semiconducting 1:1 Salts of 1,1'-Disubstituted Ferrocenes and [Ni(mnt)₂]^-. Synthesis, Structure, and Physical Properties”, Organometallics 1996, 15, 5342-5346.

J. Spencer, V. Gramlich, R. Häusel, A. Togni, “Synthesis of P,S,O-Ligands Incorporating a Planar Chiral Ferrocenyl Motif”, Tetrahedron: Asymmetry 1996, 7, 41-44.

1995

A. Togni, T. Hayashi, Eds., Ferrocenes: Homogeneous Catalysis, Organic Synthesis, Materials Science, VCH, Weinheim (New York), 1995.

A. Schnyder, L. Hintermann, A. Togni, “Strong Ligand Electronic Effects on Enantioselectivity in Rhodium-Catalyzed Hydroboration with Novel Pyrazole-Containing Ferrocenyl Ligands”, Angew. Chem. Int. Ed. Engl. 1995, 34, 931-933; Angew. Chem. 1995, 107, 996-998.

S. Bronco, G. Consiglio, S.D. Benedetto, M. Fehr, F. Spindler, A. Togni, “Enantioselective Alternating Olefin-Carbon Monoxide Copolymerization: A New Concept for Activity and Stereoselectivity”, Helv. Chim. Acta 1995, 78, 883-886.

H.C.L. Abbenhuis, U. Burckhardt, V. Gramlich, C. Köllner, R. Salzmann, P.S. Pregosin, A. Togni, “Successful Application of a ”Forgotten” Phosphine in Asymmetric Catalysis: a 9-Phospha-[3.3.1]-bicyclonon-9-yl Ferrocene Derivative as Chiral Ligand”, Organometallics 1995, 14, 759-766.

U. Burckhardt, L. Hintermann, A. Schnyder, A. Togni, “Synthesis and Structure of Pyrazole-Containing Ferrocenyl Ligands for Asymmetric Catalysis”, Organometallics 1995, 14, 5415-5425.

P. Barbaro, A. Togni, “A New Chiral Tridentate Ferrocenyl Ligand. Synthesis and Characterization of its Pd(II) and Ni(II) Complexes”, Organometallics 1995, 14, 3570-3573.

P.S. Pregosin, R. Salzmann, A. Togni, “³¹P, ¹³C, and ¹H NMR Studies on Chiral Allyl Ferrocenylphosphine Complexes of Pd(II)”, Organometallics 1995, 14, 842-847.

1994

A. Togni, L.M. Venanzi, “Nitrogen Donors in Organometallic Chemistry and Homogeneous Catalysis”, Angew. Chem. Int. Ed. Engl. 1994, 33, 497-526; Angew. Chem. 1994, 106, 517-547.

A. Togni, F. Spindler, G. Rihs, N. Zanetti, M.C. Soares, T. Gerfin, V. Gramlich, “Synthesis and Coordination Chemistry of New Chiral Ferrocenyl Phosphines for Asymmetric Catalysis”, Inorg. Chim. Acta (Topical Volume - Metals in Organic Synthesis) 1994, 222, 213-224.

C. Breutel, P.S. Pregosin, R. Salzmann, A. Togni, “An Unusual, Selective h³-h¹ Allyl Isomerization in a Chiral Allylic Alkylation Catalyst”, J. Am. Chem. Soc. 1994, 116, 4067-4068.

A. Togni, C. Breutel, A. Schnyder, F. Spindler, H. Landert, A. Tijani, “A Novel Easily Accessible Chiral Ferrocenyldiphosphine for Highly Enantioselective Hydrogenation, Allylic Alkylation, and Hydroboration Reactions”, J. Am. Chem. Soc. 1994, 116, 4062-4066.

F. Gorla, A. Togni, L.M. Venanzi, A. Albinati, F. Lianza, “The synthesis of an Optically Active Platinum(II)-Complex Containing a New Terdentate P-C-P Ligand and Its Catalytic Activity in the Asymmetric Aldol Reaction of Methyl Isocyanoacetate. The X-ray Crystal Structure of [2,6-Bis(1'S,2'S-1'-diphenylphosphino-2',3'-O-isopropylidene-2',3'-dihydroxypropyl) phenyl](nitrato)platinum(II)”, Organometallics 1994, 13, 1607-1616.

H.C.L. Abbenhuis, A. Togni, B. Müller, A. Albinati, U. Burckhardt, V. Gramlich, “A New Stereoselective Approach to Chiral Ferrocenyl Ligands for Asymmetric Catalysis”, Organometallics 1994, 13, 4481-4493.

A. Togni, M. Hobi, G. Rihs, G. Rist, A. Albinati, P. Zanello, D. Zech, H. Keller, “1,1'-Disubstituted Ferrocenes as Donors for Charge-Transfer Complexes. Synthesis, Structure, Conductuvity, and Magnetic Properties”, Organometallics 1994, 13, 1224-1234.

1993

R.E. Blumer, P.S. Pregosin, H. Rüegger, A. Togni, “One and Two-dimensional Solution and Solid State NMR Studies of Di- and Trinuclear Optically Active Ferrocenylphosphine Complexes of Mercury(II)”, Inorg. Chem. 1993, 32, 2663-2669.

M. Bovens, A. Togni, L.M. Venanzi, “Asymmetric Allylic Alkylation with Palladium Coordinated to a New Optically Active Pyrazolylmethane Ligand”, J. Organomet. Chem. 1993, 451, C28-C31.

A. Togni, G. Rist, G. Rihs, A. Schweiger, “EPR , ¹H and ¹³C ENDOR , ¹⁴N ESEEM, and X-Ray Crystallographic Studies of Oxovanadium(IV)-bis(1R-3-Heptafluorobutyrylcamphorato): A Catalyst for Asymmetric Hetero Diels-Alder Reactions”, J. Am. Chem. Soc. 1993, 115, 1908-1915.

A. Togni, G. Rihs, “Synthesis and Structure of Enantiomerically Pure Ferrocene Derivatives for Nonlinear Optics”, Organometallics 1993, 12, 3368-3372.

1981-1992

P.S. Pregosin, A. Togni, L.M. Venanzi, “New Tungsten-Iridium Dinuclear Complexes Containing Cyclopentadienyl and Hydrido Bridges”, Angew. Chem. Int. Ed. Engl. 1981, 20, 668-669; Angew. Chem. 1981, 93, 684-685.

A. Albinati, R. Naegeli, A. Togni, L.M. Venanzi, “Mono- and Dihydrido-Bridged Tungsten-Platinum Complexes”, Organometallics 1983, 2, 926-928.

H. Lehner, D. Matt, A. Togni, R. Thouvenot, L.M. Venanzi, A. Albinati, “New Cationic Rhodium(I)-Iridium(III) Complexes with Bridging Hydride and Chloride Ligands. Synthesis and X-Ray Crystal Structure of [(diphos)Rh(µ-Cl)IrCl(PEt₃)₃]BF₄ and [(diphos)Rh (µ-H)(µ-Cl)IrH(PEt₃)₃]BF₄”, Inorg. Chem. 1984, 23, 44254-4261.

A. Albinati, K.-H. Dahmen, A. Togni, L.M. Venanzi, “Ein neuer Sandwich-Komplex-Typ aus Ag(I) und [Pt₃(µ-CO)₃(PiPr₃)₃]”, Angew. Chem. 1985, 97, 760-761.

A. Albinati, H. Moriyama, H. Rüegger, P.S. Pregosin, A. Togni, “Platinum(II) Trichlorostannate Complexes with Nitrogen Ligands. ¹⁹⁵Pt, ¹¹⁹Sn, ³¹P, and ¹⁵N NMR Studies and the X-Ray Crystallographic Structure of(p-Chloroaniline)-(triethylphosphine)- chloro(trichlorostannato)platinum(II)”, Inorg. Chem. 1985, 24, 4430-4433.

M. Kretschmer, P.S. Pregosin, A. Albinati, A. Togni, “Hydrido-1,5-Cyclooctadieneiridium(III) Complexes Stabilized by Trichlorostannate Ligands and the Structure of [IrH₂(SnCl₃) (PPh₃)₃]”, J. Organomet. Chem. 1985, 281, 365-378.

A. Albinati, A. Togni, L.M. Venanzi, “Cationic Molybdenum(IV)- and Tungsten(IV)-Iridium(III) Complexes with Hydride and h⁵:h¹-Cyclo-pentadienyl Bridging Ligands. Syntheses and X-Ray Crystal Structure of [(h⁵-C₅H₅)M(µ-H)₂ (µ-(h⁵:h¹-C₅H₄))IrH(PMePh₂)₂][PPh₄] (M=Mo, W)”, Organometallics 1986, 5, 1785-1791.

A. Albinati, R. Naegeli, A. Togni, L.M. Venanzi, “Mono-and Di-Hydrido-Bridged Platinum(II)-Tungsten(IV) Complexes. Synthesis and X-Ray Crystal Structure of [Cp₂W(µ-H)₂PtPh(PEt₃)] [BPh₄] and [Cp₂(H)W(µ-H)PtPh(PEt₃)₂][BPh₄]”, J. Organomet. Chem. 1987, 330, 85-100.

M. Riediker, A. Hafner, U. Piantini, G. Rihs, A. Togni, “Structure of Chloro(cyclopentadienyl)bis(1,2:5,6-di-O-isopropylidene-a-D-gluco- furanos-3-O-yl) Titanate, a Novel Titanium-Carbohydrate Complex”, Angew. Chem. Int. Ed. Engl. 1989, 28, 499-500; Angew. Chem. 1989, 101, 493-494.

A. Togni, S.D. Pastor, G. Rihs, “Application of the Gold(I)-Catalyzed Aldol Reaction to a Stereoselective Synthesis of (2S,3R,4R,6E)-3-Hydroxy-4-methyl-2-(methylamino)-oct-6-enoic Acid (=MeBmt), Cyclosporin's Unusual Amino Acid”, Helv. Chim. Acta 1989, 72, 1471-1478.

A. Togni, S.D. Pastor, “Enantioselective Synthesis: Steric and Electronic Effects of the Substrates upon Stereoselectivity in the Gold(I)-Catalyzed Aldol Reaction with Chiral Ferrocenylamine Ligands”, Helv. Chim. Acta 1989, 72, 1038-1042.

S.D. Pastor, A. Togni, “Sterically Congested Ligands: Synthesis and Spectral Characterization of the First Pd(II) and Pt(II) Complexes of Tetra-t-butyl-substituted Biaryloxybis(1,3,2-oxazaphospholidines)”, Inorg. Chim. Acta 1989, 159, 3-6.

S.D. Pastor, A. Togni, “Asymmetric Synthesis with Chiral Ferrocenylamine Ligands: The Importance of Central Chirality”, J. Am. Chem. Soc. 1989, 111, 2333-2334.

A. Togni, S.D. Pastors, “Enantioselective Synthesis of b-Hydroxy-a-aminophosphonic Acid Precursors”, Tetrahedron Lett. 1989, 30, 1071-1072.

A. Togni, G. Rihs, P.S. Pregosin, C. Ammann, “Synthesis, Structure and 2D-NMR Studies of Novel Chiral Palladium(II)-(h³-Allyl) Complexes Containing the Bidentate Ligand Sparteine”, Helv. Chim. Acta 1990, 73, 723-732.

A. Togni, S.D. Pastor, “Chiral Cooperativity: The Nature of the Diastereoselective and Enantioselective Step in the Gold(I)-Catalyzed Aldol Reaction Utilizing Chiral Ferrocenylamine Ligands”, J. Org. Chem. 1990, 55, 1649-1664.

A. Togni, S.D. Pastor, G. Rihs, “Enantioselective Synthesis: Catalysis of the Aldol Reaction by Neutral Gold(I)-Chiral Ferrocenylphosphine Complexes. Crystal Structure of the Complex [{(h⁵-C₅H₄PPh₂)(h⁵-C₅H₃(PPh₂)-CH(Me)-CH₂CH₂NMe₂)Fe}₂-(AuCl)₃]·Et₂O”, J. Organomet. Chem. 1990, 381, C21-C25.

A. Togni, “Asymmetric Hetero Diels-Alder Reactions Catalyzed by Novel Chiral Vanadium(IV) Bis(1,3-diketonato) Complexes”, Organometallics 1990, 9, 3106-3113.

A. Togni, R. Häusel, “A New Entry into Sulfur Containing Ferrocenylphosphine Ligands for Asymmetric Catalysis”, Synlett 1990, 633-635.

S.D. Pastor, A. Togni, “Asymmetric Synthesis: Modification of Chiral Ferrocenylamine Ligands for the Gold(I)-Catalyzed Aldol Reaction”, Tetrahedron Lett. 1990, 31, 839-840.

A. Togni, S.D. Pastor, “Cooperativity of Chirality in Homogeneous Catalysis: The Gold(I)-Catalyzed Aldol Reaction and the Vanadium(IV)-Catalyzed Hetero Diels-Alder Cycloaddition”, Chirality 1991, 3, 331-340.

S.D. Pastor, R.K.Rodebaugh, P.A. Odorisio, B. Pugin, G. Rihs, A. Togni, “Sterically Congested Molecules: 2,2'-[(Biaryldiyl)bis(oxy)]bis-[1,3,2-oxazaphospholidines]”, Helv. Chim. Acta 1991, 74, 1175-1193.

S.D. Pastor, A. Togni, “Chiral Cooperativity: The Effect of Distant Chiral Centers in Ferrocenylamine Ligands upon Enantioselectivity in the Gold(I)-Catalyzed Aldol Reaction”, Helv. Chim. Acta 1991, 74, 905-933.

A. Togni, P.S. Pregosin, R. Blumer, “2D NMR Conformational Studies on Chiral Ferrocenylphosphine Ligands for the Asymmetric Gold(I)-Catalyzed Aldol Reaction”, Helv. Chim. Acta 1991, 74, 1533-1543.

A. Togni, “Asymmetric Allylic Alkylation Catalyzed by Palladium-Sparteine Complexes”, Tetrahedron: Asymmetry 1991, 2, 683-690.

S.D. Pastor, R. Kesselring, A. Togni, “The Gold(I)-Catalyzed Aldol Reaction Utilizing Chiral Ferrocenylamine Ligands: Synthesis of N-Benzyl-Substituted Ligands”, J. Organomet. Chem. 1992, 429, 415-420.

A. Togni, G. Rihs, R.E. Blumer, “Thiolato Ligands Derived from Chiral Ferrocenylphosphines: Synthesis and Structure of the Trimeric Copper(I) Complex [CpFe(h⁵-C₅H₃(1-PPh₂)-(2-CH(CH₃)S)Cu]₃”, Organometallics 1992, 11, 613-621.